上氟科技欢迎您!
联系方式
客服电话: 021-65170832
销售热线: 180-1971-6620 
173-0172-9617 
133-3198-3812 

199-5563-9105 
QQ服务: 在线客服  在线客服  在线客服  在线客服

Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis

文件下载:
Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis

Lei Zhu,*a Lian-Sheng Wang,a Bojie Li,a Boqiao Fu,a Cheng-Pan Zhang*b and Wei Lia
Chem. Commun., 2016, 52, 6371.



We report herein a single component Ir photoredox catalyst which
is capable of catalyzing the hydrotrifluoromethylation of terminal
alkenes and Michael acceptors with sodium triflinate (Langlois
reagent) in methanol under irradiation at room temperature. Various
synthetically useful functional groups, including ester, amide, ether,
aldehyde, sulfone, ketone and aryl boronate, are well tolerated in
this reaction.
Copyright © 2015 上氟科技
沪ICP备11018706号-3
技术支持:库价化学(KuuJia)